0.1 mole H3POx is completely neutralised by 5.6 g KOH then the true statement is:

0.1 mole H3POx is completely neutralised by 5.6 g KOH then the true statement is:

  1. A

    x = 3 and given acid is dibasic

  2. B

    x = 4 and given acid has no P-H linkage

  3. C

    x = 2 and given acid does not form acid salt

  4. D

    all of these

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    Solution:

    If x = 4
    H3PO4+3KOHK3PO4+3H2O
    0.1 mole → 0.3 mole
    If x = 3
    H3PO3+2KOHK2HPO3+2H2O
    0.1 mole → 0.2 mole
    If x=2
    H3PO2+KOHKH2PO2+H2O
    0.1 mole→0.1 mole
    So, if x = 2, 5.6g KOH will be required.

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