UncategorizedAcetic acid reacts with PCl5 to form:

Acetic acid reacts with PCl5 to form:


  1. A
    CH2ClCOOH
  2. B
    CHCl2COOH
  3. C
    CH3COCl
  4. D
    CH3COOCl 

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    Solution:

    Concept- Acetyl chloride is produced by heating acetic acid with phosphorus pentachloride. The COOH group is changed to the COCl group in this reaction.
      CH3COOH + PCl5 = CH3COCl+HCl +POCl3
    The general reaction given by carboxylic acid is nucleophilic addition elimination
    also known as acyl substitution
    Acyl chlorides :
    most reactive of the acid derivatives
    They have chloride ions with excellent leaving groups that are protonated to the carbonyl carbon atom.
    The carbonyl carbon atom undergoes nucleophilic addition as the reaction's first step, followed by an elimination that regenerates the carbon-oxygen double bond.
    Hence, the correct option is 3.
     
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