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An octahedral complex with molecular composition M5NH3ClSO4 has two isomers, A and B. The solution of A gives a white precipitate with AgNO3 solution and the solution of B gives white precipitate with BaCl2 solution. The type of isomerism exhibited by the complex is:

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a
Linkage isomerism
b
Ionisation isomerism
c
Coordinate isomerism
d
Geometrical isomerism

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detailed solution

Correct option is B

The complexes are MNH3SO4(A)Cl and  MNH3Cl(B)SO4.These structures represent ionisation isomers and the phenomenon is ionisation isomerism.

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