Brine when saturated first with NH3 and then with CO2 gives a mixture which when filtered gives a white residue (A) and the filtrate (B). Solid(A) when strongly heated gives a white solid (C). The solids (A) and (C) are respectively

Brine when saturated first with NH3 and then with CO2 gives a mixture which when filtered gives a white residue (A) and the filtrate (B). Solid(A) when strongly heated gives a white solid (C). The solids (A) and (C) are respectively

  1. A

    Na2CO3.10H2O ; NaHCO3

  2. B

    NaHCO3 ; Na2CO3.10H2O

  3. C

    NaHCO3 ; Na2CO3

  4. D

    Na2CO3 ;  NaHCO3

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    Solution:

    Preparation of Na2CO3 by solvay process involves the following reactions :

    2NH+ CO2 + H2(NH4)2CO3

     (NH4)2CO3 + CO2 + H22NH4HCO3

    2NaCl + 2NH4HCO3 2NaHCO3(A) +2NH4Cl (B)

    2NaHCO3 (A)heatNa2CO3(C) + CO2 + H2O

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