Certain buffer solution contains equal concentration of X- and HX. Kb for X−is 10−10. Calculate pH of buffer

Certain buffer solution contains equal concentration of X- and HX. Kb for Xis 1010. Calculate pH of buffer

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    Solution:

     KbX=1010 and for conjugate acid-base pair 

    Ka(HX)×KbX=1014Ka(HX)=104 

    But [HX]= (acid) =X(salt) 

    Now using Handerson's equation 

     pH=logKa+log[ Salt ][ Acid ]pH=log104=4

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