Consider the following balanced reactions :
 (i) K2PtCl4+2NH3 ' X ' +2KCl  (ii) PtNH34NO32+2KCl ' Y ' +2NH3+2KNO3
Both X and Y have same molecular formula Pt.2NH3 .Cl2 and X is more soluble in polar solvent such as ethanol while Y is soluble in non-polar solvent like petroleum, ether and CCl4.
Complex X and Y are :

  1. A

    ionization isomers

  2. B

    geometrical isomers

  3. C

    solvate isomers

  4. D

    co-ordination isomers

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    Solution:

     The formula for complex compounds ' X ' and ' Y ' is 
    PtCl2NH32
     As compound is neutral co-ordination compound therefore it does not exhibit ionization isomerism, solvate isomerism and co-ordination isomerism.
    Complex compound exhibit geometrical isomerism

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