Given are the following informations at 298 K.

$\begin{array}{l}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}{\mathrm{N}}_2{\mathrm{O}}_4\left(\mathrm{g}\right)\rightleftharpoons 2{\mathrm{NO}}_2\left(\mathrm{g}\right)\\ {\mathrm{\Delta }}_{\mathrm{f}}{H}^{\circ }/\mathrm{kJ}{\mathrm{mol}}^{-1}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}9.16\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}33.18\\ {\mathrm{\Delta }}_{\mathrm{f}}{G}^{\circ }/\mathrm{kJ}{\mathrm{mol}}^{-1}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}97.54\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}\hspace{0.25em}51.31\end{array}$

The reaction is carried out in a closed vessel starting from ${\mathrm{N}}_2{\mathrm{O}}_4$.

The total pressure of the system at equilibrium will be

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