In the following disproportionation of Cl2 in basic mediumCl2 + 2KOH  →  KCl  + KClO + H2OEquivalent mass of  Cl2 is

In the following disproportionation of Cl2 in basic medium

Cl2 + 2KOH    KCl  + KClO + H2O

Equivalent mass of  Cl2 is

  1. A

    35.50

  2. B

    71.00

  3. C

    47.33

  4. D

    11.83

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    Solution:

    In a disproportionation reaction

    new equivalent mass = E (oxidation part) + E (reduction part)

     

         Change in O.N.Equivalent weight
    12 Cl20    Cl--1               1          =M2
    12 Cl20    ClO-+1                1          =M2

    Net = M2 + M2 = M = 71.0

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