In the reaction : Pb3O4 + 8HCl → 3PbCl2 + Cl2 + 4H 2O, the oxidation state of lead changes from

In the reaction : Pb3O4 + 8HCl → 3PbCl2 + Cl2 + 4H 2O, the oxidation state of lead changes from

  1. A

    +2 to zero

  2. B

    +2 to +4

  3. C

    +4 to +2

  4. D

    +4 to zero

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    Solution:

    Pb3O4 is a mixed oxide. It exist as PbO2.2PbO
    Pb3O4+ 8HCl → 3PbCl2 + Cl2 + 4H2O
    This reaction can be split into
    A) 

    large mathop {2PbO}limits^{ + 2} ; + ;4HCl; to ;mathop {2PbC{l_2}}limits^{ + 2} ; + ;2{H_2}O


    B) 

    large mathop {Pb{O_2}}limits^{ + 4} ; + ;4HCl; to ;mathop {PbC{l_2}}limits^{ + 2} ; + ;C{l_2}; + ;2{H_2}O


    Oxidation state of Pb changes from +4 to +2

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