K1, K2 and K3 are the equilibrium constants of the following reactions (I), (II) and (III) respectively:(I)    N2+2O2⇌2NO2 (II)  2NO2⇌N2+2O2 (III) NO2⇌12N2+O2The correct relation from the following is

K1, K2 and K3 are the equilibrium constants of the following reactions (I), (II) and (III) respectively:

(I)    N2+2O22NO2 (II)  2NO2N2+2O2 (III) NO212N2+O2

The correct relation from the following is

  1. A

    K1=1K2=1K3

  2. B

    K1=1K2=1K32

  3. C

    K1=K2=K3

  4. D

    K1=1K2=K3

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    Solution:

    (I) N2+2O2K12NO2

    K1=NO22N2O22      . . . .(i)

    (II) 2NO2K2N2+2O2 

    K2=N2O22NO22         . . . (ii)

    (III) NO2K312N2+O2

    K3=N21/2O2NO2

    K32=N2O22NO22

    from equation (i), (ii) and (iii)

    K1=1K2=1K32

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