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PhenolNaOHA2)H+1)CO2BH+CH3CO2OC .

Incorrect statement among the following is

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a
Preparation of ‘B’ from phenol is called Kolbe’s reaction
b
‘B’ is steam volatile
c
‘C’ has a free  Phenolic– OH group of ‘B’
d
‘C’ has a free – OH group of COOH

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detailed solution

Correct option is C

‘B’ is salicylic acid. Salicylic acid forms when phenol is reacted with NaOH/CO2 follows by acidic treatment. This reaction also known as Kolbe's reaction. It is a steam volatile compound.

 ‘C’ is Aspirin (acetylsalicylic acid) and it has a free – OH group of COOH.

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