Solubility of AgCl in water, 0.01 M CaCl2, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3 and S4 respectively, then

Solubility of AgCl in water, 0.01 M CaCl2, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3 and S4 respectively, then

  1. A

    S1 > S2  > S3  > S4

  2. B

    S1 > S3  > S2  > S4

  3. C

    S1 > S2  = S3  > S4

  4. D

    S1 > S3  > S4  < S2

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    Solution:

    AgCl     Ag+   +  Cl-

    In   CaCl2

    CaCl2     Ca+2   +  2Cl-

    0.01               0.01         2 x 0.01

    In NaCl

    NaCl     Na+   +  Cl-

    0.01           0.01          0.01  

    In   AgNO3

    AgNO3     Ag+   +  NO3¯

    0.05               0.05          0.05

    common ion effect is maximum in  AgNO3

    So,  S1 > S3  > S2  > S4

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