Statement 1 : In the reaction,3As2S3 + 28HNO3 + 4H2O→  6H3AsO4 + 9H2SO4 + 28NOelectrons transferred are 84.Statement 2 : As is oxidized from +3 to +5 and sulphur from -2 to +6

Statement 1 : In the reaction,

3As2S3 + 28HNO3 + 4H2O  6H3AsO4 + 9H2SO4 + 28NO

electrons transferred are 84.

Statement 2 : As is oxidized from +3 to +5 and sulphur from -2 to +6

  1. A

    Both Statement 1 and Statement 2 are true.

  2. B

    Statement 1 is true and Statement 2 is false.

  3. C

     Statement 1 is false and Statement 2 is true.

  4. D

    Both  Statement 1 and Statement 2  are false.

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    Solution:

    As3+2   2As5+ + 4e-           S2-3   3S6+ + 24e- ______________________________ As2S3   2As5++ 3S6+ + 28 e-  × 3 3e- + N5+   N2+ ×28

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