The decomposition of N2O4  to  NO2 is carried out at 280 K in chloroform. When equilibrium has been established, 0.2 mol of N2O4  and 2 × 10-3  mol of  NO2 are present in 2 litre solution. The equilibrium constant for reaction N2O4  ⇌  2NO2 is

The decomposition of N2O4  to  NO2 is carried out at 280 K in chloroform. When equilibrium has been established, 0.2 mol of N2O4  and 2 × 10-3  mol of  NO2 are present in 2 litre solution. The equilibrium constant for reaction N2O4    2NO2 is

  1. A

    1 × 10-2

  2. B

    2 × 10-3

  3. C

    1 × 10-5

  4. D

    2 × 10-5

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    Solution:

    K=NO22N2O4 = 2 × 10-32222 = 10-610-1=10-5

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