ChemistryThe elevation of boiling point of 0.10 m aqueous CrCl3.xNH3 solution is two times that of 0.05 m aqueous CaCl2 solution. The value of x is _______________.[Assume 100% ionization of the complex and CaCl2 coordination number of Cr as 6, and that all NH3 molecules are present inside the coordination sphere]

The elevation of boiling point of 0.10 m aqueous CrCl3.xNH3 solution is two times that of 0.05 m aqueous CaCl2 solution. The value of x is _______________.

[Assume 100% ionization of the complex and CaCl2 coordination number of Cr as 6, and that all NH3 molecules are present inside the coordination sphere]

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    Solution:

    ΔTbCrCl3.XNH3=2ΔTbCaCl2CaCl2Ca2++2Cl iCaCl2=3 i=3i×Kb×0.1=2×3×Kb×0.05i=5

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