The number of electrons required to deposit 6.35 g of copper at the cathode during the electrolysis of an aqueous solution of copper sulphate will be (Given: Atomic mass of Cu= 63.5 u, NA is Avogadro constant)

The number of electrons required to deposit 6.35 g of copper at the cathode during the electrolysis of an aqueous solution of copper sulphate will be (Given: Atomic mass of Cu= 63.5 u, NA is Avogadro constant)

  1. A

    NA/20mol

  2. B

    NA/10mol

  3. C

    NA/5mol

  4. D

    NA/2mol

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    Solution:

    Amount of Cu to be deposited at the cathode is n=mM=6.35 g63.5 g mol1=0.10 mol

    Since 2 electrons are required to convert Cu2+ ion into Cu, the amount of electrons required to deposit 0.10mol of Cu will be 0.20 mol. The number of electrons required will be (0.20mol) NA i.e. NA/5mol.

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