The order of basicity of the compounds

The order of basicity of the compounds

  1. A

    IV>I>II>II

  2. B

    I>II>II>IV

  3. C

    III>I>IV>II

  4. D

    II>I>III>IV

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    Solution:

    The order of basicity is I > III > I> IV

    The lone pair of electrons on N is more readily available for protonation in I and III then in II. IlI contains an oxygen atom which has — I effect due to which it is less basic than I. In compound IV lone pair of e-s on N—atom is contributed towards the aromatic sextet formation and hence is not at all available for protonation. Hence option (2) is correct.

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