Which cycloalkane has the lowest heat of combustion per CH2 group

Which cycloalkane has the lowest heat of combustion per CH2 group

  1. A

    Cyclopropane

  2. B

    Cyclobutane

  3. C

    Cyclopentane

  4. D

    Cyclohexane

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    Solution:

    In cyclopropane. the angle strain is maximum hence it is a highly strained molecule and consequently most unstable. The angle strain in cyclobutane is less than that in cyclopropane. hence cyclobutane is more stable than cyclopropane. This stability increases up to 6 membered rings. then decreases from 7 to 11 membered rings and from the 12 membered onwards attains the stability of 6 membered ring. Heat of combustion is a method of measuring chemical stability Hence cyclohexane has the lowest heat of combustion per CH2 group. 

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