Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy?

Which of the following alkaline earth metal sulphates has hydration enthalpy higher than the lattice enthalpy?

  1. A

     CaSO4

  2. B

    BeSO4   

  3. C

    BaSO4

  4. D

    SrSO4

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    Solution:

    large Solubility;:;xrightarrow{{BeS{O_4};  data-src= ;MgS{O_4}; > ;CaS{O_4}; > ;SrS{O_4}; > ;BaS{O_4}}}">


    Hydration energy decreases solubility decreases
    Hydration energy  solubility
    In case of large size anion 

    large left[ {SO_4^{ - 2};& ;CO_3^{ - 2}} right]

    with small charge in cation size there is no considerable change in lattice energy and hence in this case solubility depends on the hydration energy
    Hint :
    In general in all IA group and IIA group compounds except fluorides and hydroxides solubility down the group decreases
    But the two exception are carbonates and bicarbonate of IA group where solubility increases
     

    large therefore

    BeSO4 is highly soluble in water

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