{"id":17293,"date":"2022-01-17T19:50:24","date_gmt":"2022-01-17T14:20:24","guid":{"rendered":"https:\/\/infinitylearn.com\/surge\/?p=17293"},"modified":"2024-10-08T12:04:38","modified_gmt":"2024-10-08T06:34:38","slug":"study-materials-jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-13-14-15-16-17-18","status":"publish","type":"post","link":"https:\/\/infinitylearn.com\/surge\/study-materials\/jee-main\/previous-year-papers-questions-with-solutions\/chemistry\/elements-of-p-block-groups-13-14-15-16-17-18\/","title":{"rendered":"JEE Main Previous Year Papers Questions With Solutions Chemistry  Elements of  p-Block: Groups 13,14,15,16,17 and 18"},"content":{"rendered":"<p><strong>1. When H<sub>2<\/sub>S is passed through Hg<sub>2<\/sub>S, we get(2002)<\/strong><br \/>\n<strong>(1)HgS        2) HgS + Hg<sub>2<\/sub>S<\/strong><br \/>\n<strong>3) Hg<sub>2<\/sub>S          4) Hg<sub>2<\/sub>S<sub>2<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25974742446_421a0b78f6_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-1\" width=\"285\" height=\"29\" \/><\/p>\n<p><strong>2. Alum helps in purifying water (2002)<\/strong><br \/>\n<strong>(1)forming Si complex with clay particles<\/strong><br \/>\n<strong>(2) sulphate part, which combines with the dirt and removes it<\/strong><br \/>\n<strong>(3)coagulating the mud particles<\/strong><br \/>\n<strong>(4)making mud water soluble<\/strong><br \/>\n<strong>Ans. <\/strong>(3) Alum furnished Al<sup>3+<\/sup> ions which bring about coagulation of negatively charged clay particles, bacteria, etc.<\/p>\n<p><strong>3. In the case of nitrogen, NC1<sub>3<\/sub> is possible but not NC1<sub>S,<\/sub> while in the case of phosphorous, PC1<sub>3<\/sub> and PC1<sub>5<\/sub> are possible. It is due to the (2002)<\/strong><br \/>\n<strong>(1)availability of vacant d orbitals in P but not in N<\/strong><br \/>\n<strong>(2)lower electronegativity of P than N<\/strong><br \/>\n<strong>(3)lower tendency of H-bond formation in P than in N<\/strong><br \/>\n<strong>(4)occurrence of P in solid while N in a gaseous state at room temperature<\/strong><br \/>\n<strong>Ans.<\/strong>(1) <sub>7<\/sub>N<sup>2<\/sup> =ls<sup>2<\/sup>2s<sup>2<\/sup>3p<sup>3<\/sup>, <sub>15<\/sub>P = 1 s<sup>2<\/sup>2s<sup>2<\/sup>2p<sup>6<\/sup>3s<sup>2<\/sup>3p<sup>3 <\/sup>In phosphorous the 3d \u2013 orbitals are available<\/p>\n<p><strong>4. Number of sigma bonds in P<sub>4<\/sub>O<sub>10<\/sub> is (2003)<\/strong><br \/>\n<strong>(1)6  2) 1            3) 17            4) 16 <strong>Ans.<\/strong><br \/>\nAns.<br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25367953464_d8c0997b93_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-4\" width=\"220\" height=\"160\" \/><\/strong><\/p>\n<p><strong>5. What happens when phosphine gas is mixed with chlorine gas?    (2003)<\/strong><br \/>\n<strong>(1)PC1<sub>3<\/sub> and HC1 are formed, and the mixture warms up<\/strong><br \/>\n<strong>(2)PC1<sub>5<\/sub> and HC1 are formed, and the mixture cools down<\/strong><br \/>\n<strong>(3)PH<sub>3<\/sub>.C1<sub>2<\/sub> is formed with warming up<\/strong><br \/>\n<strong>(4)The mixture only cools down<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/26000654815_540205fa79_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-5\" width=\"277\" height=\"37\" \/><\/p>\n<p><strong>6. Graphite is a soft solid lubricant extremely difficult to melt. The reason for this anomalous behavior is that graphite. (2003)<\/strong><br \/>\n<strong>(1)is an alio tropic form of diamond<\/strong><br \/>\n<strong>(2)has molecules of variable molecular masses like polymers<\/strong><br \/>\n<strong>(3)has carbon atoms arranged in large plates of rings of strongly bound carbon atoms with weak interplate bonds.<\/strong><br \/>\n<strong>(4)is a non-crystalline substance.<\/strong><br \/>\n<strong>Ans.<\/strong>(1) 4HC\/ + 0<sub>2\u2013&gt;<\/sub> 2Cl<sub>2<\/sub> + 2H<sub>2<\/sub>0  cloud of white fumes.<\/p>\n<p><strong> 7. Concentrated hydrochloric acid, when kept in the open air, sometimes produces a cloud of white fumes. The explanation for it is that (2003)<\/strong><br \/>\n<strong>(1)oxygen in the air reacts with the emitted HC1 gas to form a cloud of chlorine gas<\/strong><br \/>\n<strong>(2) The strong affinity of HC1 gas for moisture in air results in the formation of droplets of a liquid solution, which appears like a cloudy smoke.<\/strong><br \/>\n<strong>(3)due to a strong affinity for water. Concentrated hydrochloric acid pulls moisture of air towards itself. This moisture forms droplets of water and hence the cloud.<\/strong><br \/>\n<strong>(4)concentrated hydrochloric acid emits strongly smelling HC1 gas.<\/strong><br \/>\n<strong>Ans. <\/strong>(3) Layers are held together.<\/p>\n<div class=\"card\" style=\"text-align: center;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/test-series\/jee-12-aits?utm_source=surge&amp;utm_medium=Org&amp;utm_campaign=AITS\"><br \/>\n<img loading=\"lazy\" class=\" lazyloaded\" style=\"width: 100%; border-radius: 10px;\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/10\/class-12-jee-test-series.jpg\" alt=\"class 12 jee test series\" width=\"1201\" height=\"636\" data-src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/10\/class-12-jee-test-series.jpg\" \/><\/a><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/test-series\/jee-12-aits?utm_source=surge&amp;utm_medium=Org&amp;utm_campaign=AITS\"><button><strong>All India Test Series for Class 12 JEE Main &amp; Advanced 2025<\/strong><\/button><\/a><\/p>\n<div style=\"text-align: center;\">Boost Your Preparation With Our All India Test Series for Class 12 JEE Main &amp; Advanced 2025<\/div>\n<\/div>\n<p><strong>8. Glass is a (2003)<\/strong><br \/>\n<strong>(1) super-cooled liquid 2) gel<\/strong><br \/>\n<strong>(3)polymeric mixture<\/strong><br \/>\n<strong>(4)micro-crystalline solid<\/strong><br \/>\n<strong>Ans. <\/strong>(1) Glass is a transparent or translucent supercooled liquid.<\/p>\n<p><strong>9. For making good quality mirrors, float glass plates are used. These are obtained by floating molten glass over a liquid metal that does not solidify before the glass. The metal used can be    (2003)<\/strong><br \/>\n<strong>(1)tin           2) sodium<\/strong><br \/>\n<strong>3) magnesium               4) mercury<\/strong><br \/>\n<strong>Ans. <\/strong>(4) It is because mercury is a liquid at room temperature.<\/p>\n<p><strong>10. Which among the following factors is the most important in making fluorine the strongest oxidizing halogen? (2004)<\/strong><br \/>\n<strong>(1)Electron affinity<\/strong><br \/>\n<strong>(2)Bond dissociation energy<\/strong><br \/>\n<strong>(3)Hydration enthalpy 4) Ionization enthalpy<\/strong><br \/>\n<strong>Ans. <\/strong>(2) Lower dissociation energy of bonds in F<sub>2<\/sub>.<\/p>\n<p><strong>11. Which one of the following statements regarding helium is incorrect?   (2004)<\/strong><br \/>\n<strong>(1) It is used to fill gas balloons instead because it is lighter and non-inflammable<\/strong><br \/>\n<strong>(2)It is used in gas-cooled nuclear reactors<\/strong><br \/>\n<strong>(3)It is used to produce and sustain powerful superconducting reagents <strong>(4)It is used as a cryogenic agent for carrying out experiments at low temperatures<\/strong><br \/>\n<strong>Ans. <\/strong><\/strong>(1) Hydrogen is lightest and is noninflammable.<\/p>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25351274884_d55051e632_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-12\" width=\"362\" height=\"145\" \/><\/p>\n<p><strong>Ans. <\/strong>(4) Hydrated and coordinated aluminium cations are farmed.<\/p>\n<p><strong>13. The soldiers of Napolean&#8217;s army, while in the Alps during freezing winter, suffered a serious problem as regards the tin buttons of their uniforms. White metallic tin buttons got converted to grey powder. This transforma\u00adtion is related to(2004)<\/strong><br \/>\n<strong>(1)an interaction with the nitrogen of the air at very low temperatures<\/strong><br \/>\n<strong>(2)an interaction with water vapor contained in the humid air<\/strong><br \/>\n<strong>(3)a change in the partial pressure of oxygen in the air<\/strong><br \/>\n<strong>(4)a change in the crystalline structure of tin<\/strong><br \/>\n<strong>Ans. <\/strong>(4) Transformation of crystal structure.<\/p>\n<p><strong>14. The number of hydrogen atom(s) attached to phosphorus atom in hypophosphorous acid is<\/strong><br \/>\n<strong>(2005)<\/strong><br \/>\n<strong>(1)zero 2) two 3) one 4) three<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25905689771_509a8134d7_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-14\" width=\"175\" height=\"94\" \/><\/p>\n<p><strong>15. The correct order of the thermal stability of hydrogen halides (H \u2013 X) is                  (2005)<\/strong><br \/>\n<strong>(1)HI &gt; HBr &gt; HC1 &gt; HF<\/strong><br \/>\n<strong>(2)HF &gt; HC1 &gt; HBr &gt; HI<\/strong><br \/>\n<strong>(3)HC1 &lt; HF &gt; HBr &lt; HI<\/strong><br \/>\n<strong>(4)HI &gt; HC1 &lt; HF &lt; HBr<\/strong><br \/>\n<strong>Ans. <\/strong>(2) HF is the most stable.<\/p>\n<p><strong>16. Heating an aqueous solution of aluminium chloride to dryness will give                (2005)<\/strong><br \/>\n<strong>(1)A1C1<sub>3<\/sub> 2) A1<sub>2<\/sub>C1<sub>6<\/sub><\/strong><br \/>\n<strong>3) A1<sub>2<\/sub>0<sub>3<\/sub>    4) Al(OH)CI<sub>2<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25879869472_658f549e45_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-16\" width=\"377\" height=\"38\" \/><\/p>\n<p><strong>17. In silicon dioxide (2005)<\/strong><br \/>\n<strong>(1)Each silicon atom is surrounded by four oxygen atoms, and each oxygen atom is bonded to two silicon atoms<\/strong><br \/>\n<strong>(2)Each silicon atom is surrounded by two oxygen atoms, and each oxygen atom is bonded to two silicon atoms<\/strong><br \/>\n<strong>(3)Silicon atoms are bonded to two oxygen atoms<\/strong><br \/>\n<strong>(4)There are double bonds between silicon and oxygen atoms<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25879869422_06aae9cb24_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-17\" width=\"219\" height=\"112\" \/><\/p>\n<p><strong>18. The structure of diborane (B<sub>2<\/sub>H<sub>fi<\/sub>) contains(2005)<\/strong><br \/>\n<strong>(1)four 2c-2e bonds and two 3c-2e bonds<\/strong><br \/>\n<strong>(2)two 2c-2e bonds and four 3c-2e bonds<\/strong><br \/>\n<strong>(3)two 2c-2e bonds and two 3c-3e bonds<\/strong><br \/>\n<strong>(4)four 2c-2e bonds and four 3c-2e bonds<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25367953294_e5ea4261cc_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-18\" width=\"289\" height=\"78\" \/><\/p>\n<p><strong>19. Which of the following chemical reactions depicts the oxidizing behaviour of H<sub>2<\/sub>S0<sub>4<\/sub>?<\/strong><br \/>\n<strong>(1)2HI + H<sub>2<\/sub>S0<sub>4<\/sub> -&gt; I<sub>2<\/sub> + S0<sub>2<\/sub> + 2H<sub>2<\/sub>0 (2006)<\/strong><br \/>\n<strong>(2)Ca(OH)<sub>2<\/sub> + H<sub>2<\/sub>S0<sub>4<\/sub> CaS0<sub>4<\/sub> + 2H<sub>2<\/sub>0<\/strong><br \/>\n<strong>(3)NaCl + H<sub>2<\/sub>S0<sub>4<\/sub> NaHS0<sub>4<\/sub> + HC1<\/strong><br \/>\n<strong>(4)2PC1<sub>S<\/sub> + H<sub>2<\/sub>S0<sub>4<\/sub> 2POCl<sub>3<\/sub> + 2HC1 + S0<sub>2<\/sub>C1<sub>2<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25367953204_13a20cfdbd_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-19\" width=\"291\" height=\"61\" \/><\/p>\n<p><strong>20. A metal, M, forms chlorides in its +2 and 44 oxidation states. Which of the following statements about these chlorides is correct?<\/strong><br \/>\n<strong>(1)MC1<sub>2<\/sub> is more volatile than MC1<sub>4<\/sub> (2006)<\/strong><br \/>\n<strong>(2)MC1<sub>2<\/sub> is more soluble in anhydrous ethanol than MC1<sub>4<\/sub><\/strong><br \/>\n<strong>(3)MC1<sub>2<\/sub> is more ionic than MC1<sub>4<\/sub><\/strong><br \/>\n<strong>(4)MC1<sub>2<\/sub> is more easily hydrolyzed than MC1<sub>4<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25974742056_f64f9be861_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-20\" width=\"350\" height=\"47\" \/><\/p>\n<p><strong>21. Which of the following statements is true?<\/strong><br \/>\n<strong>(1)H3PO3 is a stronger acid than H<sub>2<\/sub>S0<sub>3<\/sub> (2006)<\/strong><br \/>\n<strong>(2)In an aqueous medium, HF is a stronger acid than HC1<\/strong><br \/>\n<strong>(3)HC10<sub>4<\/sub> is a weaker acid than HC10<sub>3<\/sub><\/strong><br \/>\n<strong>(4)HNO3 is a stronger acid than HN0<sub>2<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25700097830_a2df15dd71_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-21\" width=\"353\" height=\"65\" \/><\/p>\n<p><strong>22. What products are expected from the disproportionation reaction of hypochlorous acid?     (2006)<\/strong><br \/>\n<strong>(1)HCIO3 and C1<sub>2<\/sub>0 2) HC10<sub>2<\/sub> and HC10<sub>4<\/sub><\/strong><br \/>\n<strong>3) HC1 and C1<sub>2<\/sub>0           4) HC1 and HC10<sub>3<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25371906353_f264c1cd3e_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-22\" width=\"287\" height=\"39\" \/><\/p>\n<p><strong>23. The decreasing values of bond angles from NH<sub>3<\/sub> (106\u00b0) to SbH<sub>3<\/sub> (101\u00b0) down group-15 of the periodic table is due to        (2006)<\/strong><br \/>\n<strong>(!)increasing bp-bp repulsion<\/strong><br \/>\n<strong>(2)increasing p-orbital character in sp<sup>3<\/sup><\/strong><br \/>\n<strong>(3)decreasing lp-bp repulsion<\/strong><br \/>\n<strong>(4)decreasing electronegativity<\/strong><br \/>\n<strong>Ans. <\/strong>(4) Repulsions will be less with lower electronegativity.<\/p>\n<div class=\"card\" style=\"text-align: center;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/online-mock-tests?utm_source=surge&amp;utm_medium=interlinking\"><br \/>\n<img loading=\"lazy\" class=\" lazyloaded\" style=\"width: 100%; border-radius: 10px;\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/09\/cvc.png\" alt=\"online mock test\" width=\"1201\" height=\"636\" data-src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/09\/cvc.png\" \/><\/a><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/online-mock-tests?utm_source=surge&amp;utm_medium=interlinking\"><button><strong>Online Mock Test<\/strong><\/button><\/a><\/p>\n<div style=\"text-align: center;\">Boost Your Preparation With Our Free Online Mock Tests For IIT-JEE, NEET And CBSE Exams<\/div>\n<\/div>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25683418620_4739930845_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-24\" width=\"340\" height=\"253\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/26000654225_1b2361da67_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-24\" width=\"350\" height=\"229\" \/><\/p>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25355263833_eab8cafd3c_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-25\" width=\"381\" height=\"174\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25700097490_f05447b06d_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-25\" width=\"392\" height=\"96\" \/><\/p>\n<p><strong>26. Identify the incorrect statement among the fol\u00adlowing (2007)<\/strong><br \/>\n<strong>(1)Ozone reacts with S0<sub>2<\/sub> to give S0<sub>3<\/sub><\/strong><br \/>\n<strong>(2)Silicon reacts with aqueous NaOH in the presence of air to give NajS^ and H<sub>2<\/sub>0<\/strong><br \/>\n<strong>(3)Cl<sub>2<\/sub> reacts with an excess of NH<sub>3<\/sub> to give N<sub>2<\/sub> and HC1<\/strong><br \/>\n<strong>(4)Br<sub>2<\/sub> reacts with hot and strong NaOH solu\u00adtion to give NaBr, NaBr0<sub>4,<\/sub> and H<sub>2<\/sub>0<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25700097380_0070378d00_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-26\" width=\"375\" height=\"97\" \/><\/p>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25355263683_736323a97c_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-27\" width=\"314\" height=\"266\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25367952324_bb4119f612_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-27\" width=\"381\" height=\"210\" \/><\/p>\n<p><strong>28. Which one of the following is the correct statement?          (2008)<\/strong><br \/>\n<strong>(1)Boric acid is a protonic acid<\/strong><br \/>\n<strong>(2)Beryllium exhibits a coordination number of six.<\/strong><br \/>\n<strong>(3)Chlorides of both beryllium and aluminum have bridged chloride structures in solid phase<\/strong><br \/>\n<strong>(4)B<sub>2<\/sub>H<sub>6<\/sub>.2NH<sub>3<\/sub> is known as \u2018inorganic benzene.\u2019<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25879868372_ecf0cc6ef3_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-28\" width=\"343\" height=\"226\" \/><\/p>\n<p><strong>29. In which of the following arrangements the e sequence is not strictly according to the property written against it?      (2009)<\/strong><br \/>\n<strong>(1)C0<sub>2<\/sub> &lt; Si0<sub>2<\/sub> &lt; Sn0<sub>2<\/sub> &lt; Pb0<sub>2<\/sub> : increasing oxidising power<\/strong><br \/>\n<strong>(2)HF &lt; HC1 &lt; HBr &lt; HI : increasing acid strength<\/strong><br \/>\n<strong>(3)NH<sub>3<\/sub> &lt; PH<sub>3<\/sub> AsH<sub>3<\/sub> &lt; SbHj : increasing basic strength<\/strong><br \/>\n<strong>(4)B&lt;C&lt;0&lt;N: increasing first ionization enthalpy<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25905688631_de00244e68_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-29\" width=\"353\" height=\"67\" \/><\/p>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25351273894_f7ef15e5b0_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-30\" width=\"375\" height=\"166\" \/><br \/>\n<strong>Ans. <\/strong>(1) Xe0<sub>3<\/sub> is more stable than XeF<sub>6<\/sub>. All the remaining reactions are feasible.<\/p>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25355262933_43a66c99d1_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-31\" width=\"366\" height=\"219\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25371905593_e1050b378e_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-31\" width=\"357\" height=\"280\" \/><\/p>\n<p><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25863173012_538ea3a75a_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-32\" width=\"453\" height=\"118\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25975121666_17d3509f2c_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-32\" width=\"378\" height=\"100\" \/><\/p>\n<p><strong>33. Which of the following statements regarding sulphur is incorrect?                           (2011)<\/strong><br \/>\n<strong>(1) At 600\u00b0C the gas mainly consists of S<sub>2 <\/sub>molecules<\/strong><br \/>\n<strong>(2) The oxidation state of sulphur is never less than + 4 in its compounds<\/strong><br \/>\n<strong>(3) S, the molecule is paramagnetic<\/strong><br \/>\n<strong>(4) The vapour at 200\u00b0C consists mostly of S<sub>8 <\/sub>rings<\/strong><br \/>\n<strong>Ans.<\/strong>(2) Sulphur can exhibit \u2013 2, + 2, + 1 oxidation states also.<\/p>\n<p><strong><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25863172872_dfc51ab23a_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-34\" width=\"356\" height=\"189\" \/><\/strong><br \/>\n<strong>Ans. <\/strong>(3) Stability of VA group hybrids decreases from NH<sub>3<\/sub> to BiH<sub>3<\/sub> due to the decrease in M \u2013 H bond energy.<br \/>\nNH<sub>3<\/sub> &gt; PH<sub>3<\/sub> &gt; AsH<sub>3<\/sub> &gt; SbH<sub>3<\/sub> &gt; BiH<sub>3<\/sub><br \/>\n<strong>35. Which of the following on thermal decomposition yields a basic and an acidic oxide?          (2012)<\/strong><br \/>\n<strong>1) NaN0<sub>3<\/sub>                      2) KC10<sub>3<\/sub><\/strong><br \/>\n<strong>3) CaC0<sub>3<\/sub>                       4) NH<sub>4<\/sub>N0<sub>3<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25974740866_203f90cc9c_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-35\" width=\"319\" height=\"180\" \/><\/p>\n<p><strong><img loading=\"lazy\" class=\"\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25355262483_8e604f0073_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-elements-of-p-block-groups-1314151617-and-18-36\" width=\"367\" height=\"141\" \/><\/strong><br \/>\n<strong>Ans. <\/strong>(1) ONF and ONO<sup>\u2013<\/sup> are isoelectronic ON Cl and ONS<sup>\u2013<\/sup> are isoelectronic<\/p>\n<p><strong>37. Which one of the following properties is not shown by NO ?                                     (2014)<\/strong><br \/>\n<strong>(1) Its bond order is 2.5.<\/strong><br \/>\n<strong>(2)It is diamagnetic in a gaseous state<\/strong><br \/>\n<strong>(3)It is a neutral oxide<\/strong><br \/>\n<strong>(4)It combines with oxygen to form nitrogen dioxide<\/strong><br \/>\n<strong>Ans.<\/strong>(2) NO is paramagnetic.<\/p>\n<div class=\"card\" style=\"text-align: center;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/one-stop-solutions-for-jee-main-prep?utm_source=surge&amp;utm_medium=interlinking\"><br \/>\n<img loading=\"lazy\" class=\" lazyloaded\" style=\"width: 100%; border-radius: 10px;\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/09\/one-stop-solution-for-jee.jpg\" alt=\"One Stop Solution for JEE Prep\" width=\"1201\" height=\"636\" data-src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/09\/one-stop-solution-for-jee.jpg\" \/><\/a><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/one-stop-solutions-for-jee-main-prep?utm_source=surge&amp;utm_medium=interlinking\"><button><strong>One Stop Solution for JEE Prep<\/strong><\/button><\/a><\/p>\n<div>JEE Main One-Stop Solution: Your complete guide to acing the JEE Main exam. Get Infinity Learn expert tips, study materials, and practice tests for success.<\/div>\n<\/div>\n<p><strong>38. Among the following oxoacids, the correct decreasing order of acid strength is (2014)<\/strong><br \/>\n<strong>(1)HC10<sub>2<\/sub> &gt; HC10<sub>4<\/sub> &gt; HCIO, &gt; HOC1<\/strong><br \/>\n<strong>(2)HCIO &gt; HC10<sub>2<\/sub> &gt; HCIO3 &gt; HOCl<sub>4<\/sub><\/strong><br \/>\n<strong>(3)HC10<sub>4<\/sub> &gt; HCIO &gt; HC10<sub>2<\/sub> &gt; HOCl<sub>3<\/sub><\/strong><br \/>\n<strong>(4)HC10<sub>2<\/sub> &gt; HCIO3 &gt; HC10<sub>2<\/sub> &gt; HOC1<\/strong><br \/>\n<strong>Ans. <\/strong>(4) With an increase in unprotonated oxygen atoms, acidic strength increases.<\/p>\n<p><strong>39. In the context of the Hall-Heroult process for extracting Al, which of the following statements is false? (2015)<\/strong><br \/>\n<strong>(1)CO and C0<sub>2<\/sub> are produced in this process<\/strong><br \/>\n<strong>(2)A\/<sub>2<\/sub>0<sub>3<\/sub> is mixed with CaF<sub>2,<\/sub> which lowers the melting point of the mixture and brings conductivity<\/strong><br \/>\n<strong>(3)A\/<sup>3+<\/sup> is reduced at the cathode to form Al<\/strong><br \/>\n<strong>(4)Na<sub>3<\/sub>A\/F<sub>6<\/sub> serves as the electrolyte<\/strong><br \/>\n<strong>Ans.<\/strong>[4] A\/<sub>2<\/sub>0<sub>3<\/sub> is dissolved in cryolite, which is an electrolyte in a molten state.<\/p>\n<p><strong>40. Which among the following is the most reactive?               (2015)<\/strong><br \/>\n<strong>1) C\/<sub>2<\/sub>      2) Br<sub>2   <\/sub> 3) I<sub>2<\/sub> 4) ICI<\/strong><br \/>\n<strong>Ans.<\/strong>[4] Interhalogen compounds are polar and are more reactive.<\/p>\n<p><strong>41. Which one has the highest boiling point? (2015)<\/strong><br \/>\n<strong>(1) He 2) Ne 3) Kr (4) Xe<\/strong><br \/>\n<strong>Ans.<\/strong>[4] The boiling point increases with an increase in Molecular mass.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>1. When H2S is passed through Hg2S, we get(2002) (1)HgS 2) HgS + Hg2S 3) Hg2S 4) Hg2S2 Ans. 2. [&hellip;]<\/p>\n","protected":false},"author":7,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_yoast_wpseo_focuskw":"JEE Main Chemistry Previous Year Papers Questions With Solutions","_yoast_wpseo_title":"JEE Main Previous Year Papers Questions With Solutions Chemistry","_yoast_wpseo_metadesc":"JEE Main Previous Year Papers Questions With Solutions Chemistry Elements of p-Block: Groups 13,14,15,16,17 and 18 \u00b7 1.","custom_permalink":"study-materials\/jee-main\/previous-year-papers-questions-with-solutions\/chemistry\/elements-of-p-block-groups-13-14-15-16-17-18\/"},"categories":[21],"tags":[],"table_tags":[],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v17.9 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>JEE Main Previous Year Papers Questions With Solutions Chemistry<\/title>\n<meta name=\"description\" content=\"JEE Main Previous Year Papers Questions With 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