{"id":17387,"date":"2022-02-13T23:14:33","date_gmt":"2022-02-13T17:44:33","guid":{"rendered":"https:\/\/infinitylearn.com\/surge\/?p=17387"},"modified":"2024-12-13T15:39:31","modified_gmt":"2024-12-13T10:09:31","slug":"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes","status":"publish","type":"post","link":"https:\/\/infinitylearn.com\/surge\/jee-main\/jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes\/","title":{"rendered":"JEE Main Previous Year Papers Questions With Solutions Chemistry Alkanes ,Alkenes ,Alkynes and Arenes"},"content":{"rendered":"<h2><span style=\"color: #00ccff;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry Alkanes ,Alkenes ,Alkynes and Arenes<\/strong><\/span><\/h2>\n<p><strong>1.Which of these will not react with acetylene ?(2002)<br \/>\n1) NaOH                                 2)  Ammonical  AgB0<sub>3<\/sub><br \/>\n3) Na                                        4) HCl<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25982047395_e0c3303408_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-7\" width=\"371\" height=\"190\" \/><\/p>\n<p><strong>2.What is the product when acetylene reacts with hypochlorous acid ?    (2002)<br \/>\n1) CH3COCI                         2)   C1CH<sub>2<\/sub>CH0<br \/>\n3) Cl<sub>2<\/sub>CHCHO                        4)  C1CHCOOH<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25681489970_91c751fe62_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-8\" width=\"349\" height=\"155\" \/><\/p>\n<p><strong>3.Bottles containing C<sub>6<\/sub>H<sub>5<\/sub>I and C<sub>6<\/sub>H<sub>S<\/sub>CH<sub>2<\/sub>I lost their original tables. They were labelled A and B for testing. A and B were separately taken in test tubes and boiled with NaOH solution. The end solution in each tube was made acidic with dilute HNO<sub>a<\/sub> and then some AgN0<sub>3 <\/sub>solution was added. Substance B gave a yellow\u2019 precipitate. Which one of the following statements is true for this experiment? (2003)<br \/>\n1)AandC<sub>6<\/sub>H<sub>5<\/sub>CH<sub>2<\/sub>I<br \/>\n2)B and C<sub>6<\/sub>H<sub>5<\/sub>I<br \/>\n3)Addition of HN0<sub>3<\/sub> was unnecessary<br \/>\n4) A was C<sub>6<\/sub>H<sub>5<\/sub>I<\/strong><br \/>\n<strong>Ans.<\/strong>(4) C<sub>6<\/sub>H<sub>5<\/sub>I will not respond to silver nitrate test because C-I bond has a partial double bond character.<\/p>\n<p><strong>4. Butene-1 may be converted to butane by reaction with (2003)<br \/>\n1) Sn-HCl                  2) Zn-Hg<br \/>\n3) Pd \/H<sub>2<\/sub>                     4) Zn- HCl<\/strong><br \/>\n<strong>Ans.<\/strong>(3) Hydrogenation.<\/p>\n<p><strong>5.Which one of the following has the minimum boiling point ?   (2004)<br \/>\n1) n-butane                                                2)  isobutane<br \/>\n3) 1-butene                                               4) 1-butyne<\/strong><br \/>\n<strong>Ans.<\/strong>(2) Lower van der Waals forces.<\/p>\n<div class=\"card\" style=\"text-align: center;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/test-series\/jee-12-aits?utm_source=surge&amp;utm_medium=Org&amp;utm_campaign=AITS\"><br \/>\n<img loading=\"lazy\" class=\" lazyloaded\" style=\"width: 100%; border-radius: 10px;\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/10\/class-12-jee-test-series.jpg\" alt=\"class 12 jee test series\" width=\"1201\" height=\"636\" data-src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/10\/class-12-jee-test-series.jpg\" \/><\/a><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/test-series\/jee-12-aits?utm_source=surge&amp;utm_medium=Org&amp;utm_campaign=AITS\"><button><strong>All India Test Series for Class 12 JEE Main &amp; Advanced 2025<\/strong><\/button><\/a><\/p>\n<div style=\"text-align: center;\">Boost Your Preparation With Our All India Test Series for Class 12 JEE Main &amp; Advanced 2025<\/div>\n<\/div>\n<p><strong>6.Which one of the following reduced with zinc and hydrochloric acid to give the <sub> <\/sub>corresponding hydrocarbon  ?   (2004)<br \/>\n1) Ethyl acetate                     2) Butan-2-one<br \/>\n3) Acetamide                         4) Acetic acid<\/strong><br \/>\n<strong>Ans.<\/strong>(2) Total reduction of carbonyl.<\/p>\n<p><strong>7.2 methylbutane on reacting with bromine in the presence of sunlight gives mainly (2005)<br \/>\n1)1- bromo -2 \u2013 methylbutane<br \/>\n2)2 \u2013 bromo -2 \u2013 methylbutane<br \/>\n3)2- bromo -3 \u2013 methylbutane<br \/>\n4)1 \u2013 bromo -3 \u2013 methylbutane<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25681489880_714fd5aed0_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-9\" width=\"373\" height=\"106\" \/><\/p>\n<p><strong>8.Acid catalyzed hydration of alkenes except ethene leads to the formation of (2005)<br \/>\n1)Primary alcohol<br \/>\n2)Secondary or tertiary alcohol<br \/>\n3)Mixture of primary and secondary alcohols<br \/>\n4)Mixture of secondary and tertiary alcohols<\/strong><br \/>\n<strong>Ans.<\/strong>(4) concept of hydration.<\/p>\n<p><img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25982048795_afbe8da9be_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-1\" width=\"485\" height=\"157\" \/><br \/>\n<strong>Ans.<\/strong>(1) Conjugated acid of Cl<sup>\u2013<\/sup> is a stronger acid. The acid is HCl.<\/p>\n<p><strong>10.Elimination of bromine from 2-bromobutane results in the formation of-       (2005)<br \/>\n1)Equimolar mixture of 1 and 2-butene<br \/>\n2)Predominantly 2-butene<br \/>\n3)Predominantly 1-butene<br \/>\n4)Predominantly 2-butyne<\/strong><br \/>\n<strong>Ans.<\/strong>(2) Saytzeff\u2019s product.<\/p>\n<p style=\"text-align: center;\"><button style=\"width: 50%;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/one-stop-solutions-for-jee-main-prep?utm_source=surge&amp;utm_medium=interlinking\"><strong>Enroll Now to One Stop Solutions for IIT JEE Prep<\/strong><\/a><\/button><\/p>\n<p><strong>11.HBr reacts with CH<sub>2<\/sub> = CH \u2013 OCH<sub>3<\/sub> under anhydrous conditions at room temperature to give<br \/>\n1)CH<sub>3<\/sub>CHO and CH<sub>3<\/sub>Br<br \/>\n2)BrCH<sub>2<\/sub>CHO and CH<sub>3<\/sub>OH<br \/>\n3)BrCH<sub>2<\/sub> \u2013 CH<sub>2<\/sub> \u2013 OCH<sub>3<\/sub><br \/>\n4)H<sub>3<\/sub>C \u2013 CHBr \u2013 OCH<sub>3<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong>(4) Electrophilic addition reaction is more favourable.<br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861253302_a039f28ebb_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-10\" width=\"369\" height=\"117\" \/><\/p>\n<p><img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25887095701_233176acac_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-2\" width=\"507\" height=\"273\" \/><br \/>\n<strong>Ans.<\/strong>(2) Ethylene<\/p>\n<p><strong>13.Which of the following reactions will yield 2, 2-dibromopropane ?    (2007)<br \/>\n1)CH<sub>3<\/sub> \u2013 C = CH + 2HBr \u2014&gt;<br \/>\n2)CH<sub>3<\/sub>CH = CHBr + HBr -&gt;<br \/>\n3)CH = CH + 2HBr \u2014&gt;<br \/>\n4)CH<sub>3<\/sub> \u2013 CH = CH<sub>2<\/sub> + HBr -&gt;<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25353333843_edf069eb64_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-11\" width=\"370\" height=\"128\" \/><\/p>\n<p><strong>14.The reaction of toluene with Cl<sub>2<\/sub> in presence of FeCl<sub>3<\/sub> gives predominantly       (2007)<br \/>\n1)benzoyl chloride<br \/>\n2)benzyl chloride<br \/>\n3)o-and p-chlorotoluene<br \/>\n4)m-chlorotoluene<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25353333873_5c118c6e22_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-12\" width=\"401\" height=\"175\" \/><\/p>\n<p style=\"text-align: center;\"><button style=\"width: 50%;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/online-mock-tests?utm_source=surge&amp;utm_medium=interlinking\"><strong>Free Online Mock Tests For IIT-JEE, NEET And CBSE Exams<\/strong><\/a><\/button><\/p>\n<p><strong>15.Presence of a nitro group in a benzene ring (2007)<br \/>\n1)activates the ring towards electrophilic substitution<br \/>\n2)renders the ring basic .<br \/>\n3)deactivates the ring towards nucleophilic substitution<br \/>\n4)deactivates the ring towards electrophilic substitution<\/strong><br \/>\n<strong>Ans.<\/strong>(4) -N0<sub>2<\/sub> group shows -M effect. It withdraws the electron density from the ring and hence deactivate the ring towards electrophilic aro\u00admatic substitution.<\/p>\n<p><strong>16.In the following sequence of reactions, the alkene affords the compound \u2018B\u2019<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25349355864_5da7fa789d_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-3\" width=\"368\" height=\"118\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25982047165_b12582b5de_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-13\" width=\"402\" height=\"123\" \/><\/p>\n<p><img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25681490480_82eca46da1_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-4\" width=\"402\" height=\"314\" \/><br \/>\n<strong>Ans.<\/strong>(2) \u2013 N0<sub>2<\/sub> is electron withdrawing which will destabilize a-complex.<\/p>\n<p><strong>18.The hydrocarbon which can react with sodium in liquid ammonia is (2008)<br \/>\n1)CH<sub>3<\/sub>CH<sub>2<\/sub>CH<sub>2<\/sub>C=CCH<sub>2<\/sub>CH<sub>2<\/sub>CH<sub>3<\/sub><br \/>\n2)CH<sub>3<\/sub>CH<sub>2<\/sub>C =CH .<br \/>\n3)CH<sub>3<\/sub>CH = CHCH<sub>3<\/sub><br \/>\n4)CH<sub>3<\/sub>CH<sub>2<\/sub>C =CCH<sub>2<\/sub>CH<sub>3<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861253152_ef2f03e096_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-14\" width=\"393\" height=\"88\" \/><\/p>\n<p><strong>19.The treatment of CH<sub>3<\/sub>MgX with CH<sub>3<\/sub>OC-H produces (2008)<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861253532_941c550fed_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-5\" width=\"345\" height=\"83\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25982047135_4856b43f37_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-15\" width=\"357\" height=\"27\" \/><\/p>\n<p><strong>20.One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular mass of 44u. The alkene is               (2010)<br \/>\n1)propene   2) 1-butene   3) 2-butene  4) ethene<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861252892_6a7b815026_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-16\" width=\"328\" height=\"93\" \/><\/p>\n<p><strong>21.Ozonolysis of an organic compound gives formaldehyde as one of the products. This confirms the presence  of :          (2011)<br \/>\n1)an isopropyl group<br \/>\n2)an acetylenic triple bond<br \/>\n3)two ethylenic double bonds<br \/>\n4)a vinyl group<\/strong><br \/>\n<strong>Ans.<\/strong>(4) Ozonolysis of an organic compound give formaldehyde when it containing atleast one vinylic double bond. HjC = CH \u2013 R.<\/p>\n<p><strong>22.2-Hexyne gives trans-2-hexene on treatment with  (2012)<br \/>\n1) Pt\/H<sub>2<\/sub>                                    2)    Li \/ NH<sub>3<\/sub><br \/>\n3) Pd \/ BaS0<sub>4<\/sub>                          4)      LiAlH<sub>4<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25353333603_21ed0c1a96_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-17\" width=\"402\" height=\"213\" \/><\/p>\n<p><strong>23.The major organic compound formed by the reaction of 1,1,1 \u2013 trichloroethane with silver powder is              (2014)<br \/>\n1) 2-Butene                             2) Acetylene<br \/>\n3) Ethene                                 4)   2-Butyne<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861252742_57c6360379_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-18\" width=\"403\" height=\"49\" \/><\/p>\n<p><strong>24.Which compound would give 5-keto-2-methyl hexanal upon ozonlysis ?<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861253472_65ea8a5dec_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-6\" width=\"382\" height=\"192\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25861252722_35ce5c561e_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes-19\" width=\"374\" height=\"80\" \/><\/p>\n<p>JEE Main Home Maths Physics Chemistry<\/p>\n","protected":false},"excerpt":{"rendered":"<p>JEE Main Previous Year Papers Questions With Solutions Chemistry Alkanes ,Alkenes ,Alkynes and Arenes 1.Which of these will not react [&hellip;]<\/p>\n","protected":false},"author":7,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_yoast_wpseo_focuskw":"","_yoast_wpseo_title":"","_yoast_wpseo_metadesc":"\"Get JEE Main Previous Year Papers Questions With Solutions Chemistry Alkanes ,Alkenes ,Alkynes and Arenes on Infinity Learn.\"","custom_permalink":"jee-main\/jee-main-previous-year-papers-questions-with-solutions-chemistry-alkanes-alkenes-alkynes-and-arenes\/"},"categories":[1],"tags":[],"table_tags":[],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v17.9 - 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