{"id":17455,"date":"2023-03-04T15:09:41","date_gmt":"2023-03-04T09:39:41","guid":{"rendered":"https:\/\/infinitylearn.com\/surge\/?p=17455"},"modified":"2025-06-03T17:29:09","modified_gmt":"2025-06-03T11:59:09","slug":"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds","status":"publish","type":"post","link":"https:\/\/infinitylearn.com\/surge\/study-material\/jee-main\/chemistry\/previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds\/","title":{"rendered":"JEE Main Previous Year Papers Questions With Solutions Chemistry Nitro,Amine and Azo Compounds"},"content":{"rendered":"<h2><span style=\"color: #0000ff;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry Nitro,Amine and Azo Compounds<\/strong><\/span><\/h2>\n<p><strong>1.When primary amine reacts with chloroform in etharioicKOH then the product is (2002)<br \/>\n1) an isocyanide                    2) an aldehyde<br \/>\n3) a cyanide                           4) an alcohol<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25704691600_27f9f79eb6_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-5\" width=\"402\" height=\"78\" \/><\/p>\n<p><strong>2.The reaction of chloroform with alcoholic KOH and p-toludine forms   (2003)<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25884758292_3a7bf351ce_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-11\" width=\"300\" height=\"150\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25372551264_a4486cab24_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-6\" width=\"403\" height=\"195\" \/><\/p>\n<p style=\"text-align: center;\"><button style=\"width: 50%;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/online-mock-tests?utm_source=surge&amp;utm_medium=interlinking\"><strong>Free Online Mock Tests For IIT-JEE, NEET And CBSE Exams<\/strong><\/a><\/button><\/p>\n<p><strong>3.The correct order of increasing basic nature for the bases NH<sub>3<\/sub>. CH<sub>3<\/sub>NH<sub>2<\/sub> and (CH<sub>3<\/sub>)<sub>2<\/sub>NH is(2003)<br \/>\n1)(CH<sub>3<\/sub> )<sub>2<\/sub> NH &lt; NH<sub>3<\/sub> &lt; CH<sub>3<\/sub>NH<sub>2<\/sub><br \/>\n2)NH<sub>3<\/sub> &lt; CH,NH<sub>2<\/sub> &lt; (CH3 )<sub>2<\/sub> NH<br \/>\n3)CH<sub>3<\/sub>NH<sub>2<\/sub> &lt; (CH<sub>3<\/sub> )<sub>2<\/sub> NH &lt; NH<sub>3<\/sub><br \/>\n4)CH<sub>3<\/sub>NH<sub>2<\/sub> &lt; NH<sub>3<\/sub> &lt; (CH<sub>3<\/sub>)<sub>2<\/sub> NH<\/strong><br \/>\n<strong>Ans.<\/strong>(2) More is the no. of +1 groups attached to N atom greater is the basic character.<\/p>\n<p><strong>4.Ethyl isocyanide on hydrolysis in acidic medium generates  (2003)<br \/>\n1)propanoic acid and ammonium salt .<br \/>\n2)ethanoic acid and ammonium salt<br \/>\n3)methylamine salt and ethanoic acid<br \/>\n4)ethylamine salt and methanoic acid<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25372551124_7d0957fc57_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-7\" width=\"439\" height=\"91\" \/><\/p>\n<p><strong>5.The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20 mL of 0.5M sodium hydroxide solution hydroxide solutio for complete neutralization. The organic compound is 1)acetamide           2) thiourea            (2004)<br \/>\n3) urea                       4) benzamide<\/strong><br \/>\n<strong>Ans.<\/strong>(3) Urea has C and N atoms in the ratio 1:2.<\/p>\n<div class=\"card\" style=\"text-align: center;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/test-series\/jee-12-aits?utm_source=surge&amp;utm_medium=Org&amp;utm_campaign=AITS\"><br \/>\n<img loading=\"lazy\" class=\" lazyloaded\" style=\"width: 100%; border-radius: 10px;\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/10\/class-12-jee-test-series.jpg\" alt=\"class 12 jee test series\" width=\"1201\" height=\"636\" data-src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2024\/10\/class-12-jee-test-series.jpg\" \/><\/a><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/test-series\/jee-12-aits?utm_source=surge&amp;utm_medium=Org&amp;utm_campaign=AITS\"><button><strong>All India Test Series for Class 12 JEE Main &amp; Advanced 2025<\/strong><\/button><\/a><\/p>\n<div style=\"text-align: center;\">Boost Your Preparation With Our All India Test Series for Class 12 JEE Main &amp; Advanced 2025<\/div>\n<\/div>\n<p><strong>6.Which of the following is the strongest base?<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/26005503985_c3b2450aa9_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-2\" width=\"374\" height=\"142\" \/><br \/>\n<strong>Ans.<\/strong>(2)1\u00b0 aliphalic amine.<\/p>\n<p><strong>7.Which one of the following methods is neither meant for the synthesis nor for separation of amines ? (2005)<br \/>\n1) Hinsberg method 2) Hofmann method 3) Wurtz reaction 4) Curtius reaction<\/strong><br \/>\n<strong>Ans.<\/strong>(3) Alkanes are obtained in Wurtz reaction.<\/p>\n<p><strong>8.Amongst the following the most basic compound is   (2005)<br \/>\n1) benzylamine                    2)    aniline<br \/>\n3) acetanilide                       4)    p-nitroaniline<\/strong><br \/>\n<strong>Ans.<\/strong>(1) -NH<sub>2<\/sub> group is not linked with benzene ring<\/p>\n<p><strong>9.An organic compound having molecular mass 60 is found to contain C=20%, H=6.67% and N=46.67% while rest is oxygen. On heating it gives NH<sub>3<\/sub> alongwith a solid residue. The solid residue give violet colour with alkaline copper sulphate solution. The compound is (2005)<br \/>\n1) CH<sub>3<\/sub>NCO           2)  CH<sub>3 CONH<sub>2<\/sub><\/sub><br \/>\n3) (NH<sub>2<\/sub>)<sub>2<\/sub>CO         4)    CH<sub>3<\/sub>CH<sub>2<\/sub>CONH<sub>2<\/sub><\/strong><br \/>\n<strong>Ans. <\/strong>(3)Emperical formula CH<sub>4<\/sub>ON<sub>2<\/sub>.<\/p>\n<p><strong>10.Fluorobenzene (C<sub>6<\/sub>H<sub>5<\/sub>F) can be synthesized in the laboratory (2006)<br \/>\n1)by heating phenol with HF and KF<br \/>\n2)from aniline by diazotisation followed by heating the diazonium salt with HBF<sub>4<\/sub><br \/>\n3)by direct fluorination of benzene with F<sub>2<\/sub> gas<br \/>\n4)by reacting bromobenzene with NaF solution<\/strong><br \/>\n<strong>Ans.<\/strong>(2) Fluordrenzene is syntherised fro C<sub>6<\/sub>H<sub>5<\/sub>HBF<sub>4<\/sub><\/p>\n<p style=\"text-align: center;\"><button style=\"width: 50%;\"><a class=\"btn btn-primary\" href=\"https:\/\/infinitylearn.com\/one-stop-solutions-for-jee-main-prep?utm_source=surge&amp;utm_medium=interlinking\"><strong>Enroll Now to One Stop Solutions for IIT JEE Prep<\/strong><\/a><\/button><\/p>\n<p><strong>11. CH<sub>3<\/sub>CH<sub>2<\/sub>NH<sub>2<\/sub>+CHa<sub>3<\/sub>+3KOH \u2013&gt;(A)+(B) + 3H20 In the chemical reaction, the compound (A) and (B) are respectively       (2007)<br \/>\n1)C<sub>2<\/sub>H<sub>5<\/sub>CN and 3KCl<br \/>\n2)CH<sub>3<\/sub>CH<sub>2<\/sub>CONH<sub>2<\/sub> and 3KCl<br \/>\n3)C<sub>2<\/sub>H<sub>5<\/sub>NC and K<sub>2<\/sub> C0<sub>3<\/sub><br \/>\n4)C<sub>2<\/sub>H<sub>5<\/sub>NC and 3KCl<\/strong><br \/>\n<strong>Ans.<\/strong>(4) It is example of carbylamine reaction. The product will be C<sub>2<\/sub>H<sub>5<\/sub><\/p>\n<p><strong>12.Which one of the following is the strongest base in aqueous solution ? (2007)<br \/>\n1) Trimethylamine            2) Aniline<br \/>\n3) Dimethylamine              4) Methylamine<\/strong><br \/>\n<strong>Ans.<\/strong>(3) In aqueous solution basicity order of 1\u00b0, 2\u00b0 and 3\u00b0 amine with methyl group is 2\u00b0 &gt; 1\u00b0 &gt; 3\u00b0.In case of aniline lone pair of nitrogen is involved in resonance, so it is weaker base than aliphatic amines.<\/p>\n<p><strong>13.Toluene is nitrated and the resulting product \u2018 is reduced with tin and hydrochloric acid. The product so obtained is diazotised and then heated with cuprotis bromide. The reaction mixture so formed contains (2008)<br \/>\n1)mixture of o \u2013 and p-bromotoluences<br \/>\n2)mixture of o- and p-dibromobenzenes<br \/>\n3)mixture of o- and p-bromoanilines<br \/>\n4)mixture of o-and m-bromotoluenes<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25884470422_dc0ee43bd3_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-8\" width=\"295\" height=\"496\" \/><\/p>\n<p><strong>14.In the chemical reactions, the compound \u2018A\u2019 and \u2018B\u2019 respectively are    (2010)<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25910298671_44b1215680_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-3\" width=\"386\" height=\"177\" \/><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25910297651_9d6ec791e9_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-9\" width=\"403\" height=\"213\" \/><\/p>\n<p><strong>15.A compound with molecular mass 180 is acylated with CH<sub>3<\/sub>COC\/ to get a compound * with molecular mass 390. The number of amino groups present per molecule of the former compound is  (2013)<br \/>\n1) 2                 2) 5                  3) 4                  4)6<\/strong><br \/>\n<strong>Ans.<\/strong><br \/>\n<img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25884470132_76d60f2855_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-10\" width=\"411\" height=\"214\" \/><\/p>\n<p><strong>16.On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is            (2014)<br \/>\n1) an alkyl isocyanide            2) an alkanol<br \/>\n3) an alkanediol                   4) an alkyl cyanide<\/strong><br \/>\n<strong>Ans.<\/strong>(1) R \u2013 NH<sub>2<\/sub> + CHC1<sub>3<\/sub> + KOH -&gt; R \u2013 NC Alkylisocyanide is obtained.<\/p>\n<p><strong>17.Considering the basic strength of amines in aqueous solution, which one has the smallest pK<sub>b<\/sub> vale ?(2014)<br \/>\n1)C<sub>6<\/sub>H<sub>5<\/sub>NH<sub>2       2) (CH<sub>3<\/sub>)<sub>2<\/sub>NH<\/sub><br \/>\n3) CH<sub>3<\/sub>NH<sub>2     4) (CH<sub>3<\/sub>)<sub>3<\/sub>N<\/sub><\/strong><br \/>\n<strong>Ans.<\/strong>(2) (CH<sub>3<\/sub>)<sub>2<\/sub>NH is a stronger base in aqueous medium than Me<sub>3<\/sub> So its pK<sub>b<\/sub> value is smallest.<\/p>\n<p><img loading=\"lazy\" src=\"https:\/\/infinitylearn.com\/surge\/wp-content\/uploads\/2021\/12\/25376514023_480bb015ca_o.png\" alt=\"jee-main-previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds-4\" width=\"400\" height=\"445\" \/><br \/>\n<strong>Ans.<\/strong>(3) Sandmayer reaction.<\/p>\n<p><strong>Also Read:<\/strong><\/p>\n<table style=\"border-collapse: collapse; width: 100%; height: 190px;\">\n<tbody>\n<tr style=\"height: 95px;\">\n<td style=\"width: 25%; height: 95px;\"><strong><a href=\"https:\/\/infinitylearn.com\/surge\/blog\/iit-jee\/jee-main-organic-chemistry-previous-year-questions-with-solutions\/\">JEE Main Organic Chemistry Previous Year Questions With Solutions<\/a><\/strong><\/td>\n<td style=\"width: 25%; height: 95px;\"><strong><a href=\"https:\/\/infinitylearn.com\/surge\/study-materials\/jee-main\/previous-year-papers-questions-with-solutions\/chemistry\/biomolecules-and-polymers\/\">JEE Main Previous Year Papers Questions With Solutions Chemistry Biomolecules and Polymers<\/a><\/strong><\/td>\n<td style=\"width: 25%; height: 95px;\"><strong><a href=\"https:\/\/infinitylearn.com\/surge\/iit-jee\/study-materials\/chemistry\/jee-main-previous-year-papers-questions-with-solutions-chemistry-general-organic-chemistry\/\">JEE Main Previous Year Papers Questions With Solutions Chemistry General Organic Chemistry<\/a><\/strong><\/td>\n<td style=\"width: 25%; height: 95px;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry in Everyday Life and Miscellaneous<\/strong><\/td>\n<\/tr>\n<tr style=\"height: 95px;\">\n<td style=\"width: 25%; height: 95px;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry Alkanes, Alkenes, Alkynes and Arene<\/strong><\/td>\n<td style=\"width: 25%; height: 95px;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry Metallurgy and Environmental Chemistry<\/strong><\/td>\n<td style=\"width: 25%; height: 95px;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry Chemical Bonding and Molecular Structure<\/strong><\/td>\n<td style=\"width: 25%; height: 95px;\"><strong>JEE Main Previous Year Papers Questions With Solutions Chemistry Alcohols,Ethers,Carobonyls and Carboxylic Acids<\/strong><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>JEE Main Previous Year Papers Questions With Solutions Chemistry Nitro,Amine and Azo Compounds 1.When primary amine reacts with chloroform in [&hellip;]<\/p>\n","protected":false},"author":7,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_yoast_wpseo_focuskw":"JEE Main Previous Year Papers Questions","_yoast_wpseo_title":"","_yoast_wpseo_metadesc":"Get JEE Main Previous Year Papers Questions With Solutions Chemistry Nitro,Amine and Azo Compounds at infinity learn","custom_permalink":"study-material\/jee-main\/chemistry\/previous-year-papers-questions-with-solutions-chemistry-nitroamine-and-azo-compounds\/"},"categories":[57,116,21],"tags":[],"table_tags":[],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v17.9 - 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