A chemical process involves decrease in enthalpy and decrease in entropy. If the magnitude of change in enthalpy is 1000 times the change in entropy, the process is spontaneous at
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a
1000°c
b
1273°c
c
729°c
d
427°c
answer is D.
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Detailed Solution
Given ΔH=−Ve and Δs=−Ve ;ΔG=ΔH−T∆SAt equilibrium, ΔG=0∴Teq=ΔHΔSTeq=10001Teq=1000KTeq=727oCΔG=ΔH−TΔSΔG=−Ve−T−VeProcess becomes spontaneous when ΔG=-Ve which is only possible when temperature is below 1000K (or) 727°c.