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Q.

A chemical process involves decrease in enthalpy and decrease in entropy. If the magnitude of change in enthalpy is 1000 times the change in entropy, the process is spontaneous at

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a

1000°c

b

1273°c

c

729°c

d

427°c

answer is D.

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Detailed Solution

Given   ΔH=−Ve  and  Δs=−Ve  ;ΔG=ΔH−T∆SAt equilibrium, ΔG=0∴Teq=ΔHΔSTeq=10001Teq=1000KTeq=727oCΔG=ΔH−TΔSΔG=−Ve−T−VeProcess becomes spontaneous when ΔG=-Ve which is only possible when temperature is below 1000K (or) 727°c.
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A chemical process involves decrease in enthalpy and decrease in entropy. If the magnitude of change in enthalpy is 1000 times the change in entropy, the process is spontaneous at