First slide

Solubility product(KSP)

Question

Let the solubilities of AgCl in H₂O, 0.01M CaCl₂, 0.01M NaCl and 0.05M AgNO₃ be S₁, S₂, S₃ and S₄ respectively. What is the correct relationship between these quantities ?

Easy

A

S₁ > S₂ > S₃ > S₄
B

S₁ > S₂ = S₃ > S₄
C

S₁ > S₃ > S₂ > S₄
D

S₄ > S₂ > S₃ > S₁

Solution

When the concentration of NaCl is less than 1 M no complexation reaction occurs with Ag⁺; but common-ion effect will be exerted on the solubility of AgCl.
In 0.05 M AgNO₃, the solubility of AgCl will be least as the [Ag⁺] is higher than the concentration of [Cl^-] in all other cases.

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