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Q.

A manometer contains a liquid of density 5.44 g/cm is attached to a flask containing gas 'A as follows If the same liquid is used in barometer to measure the atmospheric pressure, then what will be the length of the liquid column, which exerts pressure equal to 1 atm ? (density of Hg = 13.6 g/cm3)The initial pressure of gas A in the flask is:If gas A undergoes 30% trimerization 3A(g)⇌A3(g) then the difference in height of the liquid level in two columns is:

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a

190 cm

b

76 cm

c

30.4 cm

d

266 cm

e

1.5 atm

f

1 atm

g

1.3 atm

h

1.2 atm

i

38 cm

j

7.6 cm

k

3.04 cm

l

15.1 cm

answer is , , .

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Detailed Solution

hLdL=hHgdHghL=76×13.65.44=190 cmPGas=PAtm+PL=1+38190=1.2                   3Ag  ⇌       A3gt=0             1.2 atm                  A3gt=teq.           1.2−0.36   130.36=0.12 atm∴PT=1.2−0.36+0.12=0.96 atm∴The difference in height of the liquid level in twocolumns = 0.04 ×190=7.6 cm
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