To 100ml of 0.1 M AgNO3 solution, solid K2SO4 is added. The concentration of K2SO4 that shows the precipitation is (Ksp for Ag2SO4 = 6.4 × 10–5m3/l3)
0.1 M
For precipitation to occur, KIP ≥ Ksp
OR [Ag+]2 [SO4-2] = 6.4 ×10-5
[SO4-2] = 6.4×10-50.12=6.4×10-3