First slide
Gaseous state
Question

N2+3H22NH3 1 mole N2 and 4 moles H2 are taken 

in 15 L flask at 27°C. After complete conversion of N2 into NH3, 5 L of H2O is added. Pressure set up in the flask is

Moderate
Solution

                   N2+3H22NH3

Taken           1      4            0

Reacts          1     3  

H2 Ieft = 1 mol NH3 formed = 2 mol but NH3(g) dissolves in water forming NH4OH. Residual gas is only H2 which exerts pressure.

Volume = 15 - 5 = 10 L (5 L is occupied by H2O added)

 p=nVRT=1×0.0821×30010atm

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