First slide
Hess law of constant summation
Question

 N2 + O2 → 2NO, ΔH = + Q1
N2 + 2O2 → N2O4, ΔH = – Q2
NO + 1/2O2 → NO2, ΔH = – Q3
2NO2 → N2O4, ΔH = – Q4, then

Difficult
Solution

\begin{array}{l} \,\,\,\,\,\frac{1}{{eq.(1)}} \Rightarrow 2NO \to {N_2} + {O_2},\Delta {H_1} = - {Q_1}\\ \,\,\,\,\,\,eq.(2) \Rightarrow {N_2} + 2{O_2} \to {N_2}{O_4},\Delta {H_2} = - {Q_2}\\ \underline {2 \times \frac{1}{{eq.(3)}} \Rightarrow 2N{O_2} \to 2NO + {O_2},\Delta {H_3} = + 2{Q_3}} \\ \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,2N{O_2} \to {N_2}{O_4}\,\,\,,\,\Delta {H_4} = - {Q_4} = 2{Q_3} - {Q_1} - {Q_2} \end{array}

 

                                                                       

-Q_2=Q_1-2Q_3-Q_4

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