As + 20 moles H2O → Ain 20 moles H2O ; ΔH=−72kJ
As + 40 moles H2O → Ain 40 moles H2O ; ΔH = −81kJ
Enthapy of dilution when a solution containing one mole of A in 20 moles H2O is diluted by adding 20 moles of H2O to it will be
Equation (2) – Equation (1)
ΔH=−9 kJ
∵The reaction is exothermic with increase in dilution exothermic nature increases.