Statement I : Bond length in C–C > N–N > O–OStatement II : Bond enthalpy in C–C > N–N > O–O
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a
Both statements I and II are correct
b
Statement - I is correct and statement - II is incorrect
c
Statement - I is incorrect and statement - II is correct
d
Both statements I and II are incorrect
answer is A.
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Detailed Solution
Left to right in a period Atomic radius decreases∴size of C > N > O∴C–C > N–N > O–O …..Bond lengthGenerallyBond enthalpy ∝ 1Bond length∴ Expected trend of Bond enthalpy C–C < N–N < O–OBut both ‘N’ and ‘O’ contain lone pairs. Due to the repulsions between lone pairs of adjacent atoms in N–N and O–O their bond enthalpies are very low.∴Experimental bond enthalpy C–C > N–N > O–O