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Q.

Three sparingly soluble salts M2X,  MX  and MX3 have the same solubility product. Their solubilities will be in the order

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a

MX3  >  MX  > M2X

b

MX3  >  M2X  > MX

c

MX  >  MX3  > M2X

d

MX  >  M2X  > MX3

answer is B.

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Detailed Solution

M2X  →  2M+  + X-                 2s1        s1 Ksp= 4s13  or,  s1 = Ksp/41/3 MX    →    M+    +   X-,   Ksp = s22 or,   s2 = Ksp1/2 MX3    →    M3+    +   3X-                        s                3s Ksp = 27s34      or,     s3 = Ksp/271/4 Evidently, s3 > s1 > s2 Alternately  Different sparingly soluble salts having same solubility product ,salt which produces more number of ions will have more solubility.
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