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Q.

When equal volumes of following solution are mixed, precipitation of AgCl ?Ksp = 1.8 × 10-10 will occur only with

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a

10-4 M  Ag+ and  10-4 M  Cl-

b

10-5 M  Ag+ and  10-5 M  Cl-

c

10-6 M  Ag+ and  10-6 M  Cl-

d

10-10 M  Ag+ and  10-10 M  Cl-

answer is A.

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Detailed Solution

Ionic product is greater than solubility product constant precipitation occursKsp = 1.8 × 10-10Ag+ Cl- = 10-4 × 10-4=10-8 ∴   Ksp of AgCl <  Ag+ Cl-
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