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Q.

Which of the following statements is incorrect for a solution saturated with AgCl and AgBr if their solubilities in moles per litre in separate solutions are x and y respectively ?

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a

Ag+=x+y

b

Ag+=Br- + Cl-

c

Br- = y

d

Cl- > x

answer is D.

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Detailed Solution

AgCl⇌  Ag+ + Cl-      AgBr⇌   Ag+ + Br-                   x            x                            y         y                  (x + y)    x                        (x +y)   y So     Ag+ = Br- + Cl-(Since Ag is common.)
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