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The compounds of type ECl3 where E=B,P,AS(or) Bi the angles Cl-E-Cl for different E are in the order.

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By Expert Faculty of Sri Chaitanya
a
B>P=As=Bi
b
B>P>As>Bi
c
B
d
B
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detailed solution

Correct option is B

1) In BCl3 Boron undergoes sp2 Hybridization 120∘ 2) In PCl3,AsCl3&BiCl3 the central atom undergoes sp3 and one lone pair. Hence the bond angles< 109°281


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