First slide

Structural isomerism

Question

[Co(NH₃)₄Cl₂]NO₂ and [Co(NH₃)₄CI.NO₂]CI are ........ isomers

Moderate

A

Geometrical
B

Optical
C

Linkage
D

Ionization

Solution

Both produce different ions in solution state:
$\begin{array}{l} [C o {(N H_{3})}_{4} C l_{2}] N O_{2} ⇌ {[C o {(N H_{3})}_{4} C l_{2}]}^{+} + N O_{2}^{-} \\ [C O {(N H_{3})}_{4} C l . N O_{2}] C l ⇌ {[C o {(N H_{3})}_{4} C l . N O_{2}]}^{+} + C l^{-} \end{array}$

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