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Questions  

Consider the following reaction:

a)CH33CHOHCH3 conc.H2SO4

b)CH32CHCHBrCH3 alc.KOH

c) CH32CHCHBrCH3 CH33OK+

d)

 

Which of these reaction(s) will not produce Saytzeff product?

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detailed solution

Correct option is D

Reaction (C) gives Hoffman product as the major product. The reason is the nature of the base. In option C , we can see that due to the bulky nature of t-butoxide it can abstract hydrogen from stearic free position only. Hence it disobeys satzeff rule.

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