Consider the following reaction:a)CH33CHOHCH3→ conc.H2SO4b)CH32CHCHBrCH3→ alc.KOHc) CH32CHCHBrCH3→ CH33O−K+d) Which of these reaction(s) will not produce Saytzeff product?
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a
(a) ,(c) and (d)
b
(d) only
c
(b) and (d)
d
(c) only
answer is D.
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Detailed Solution
Reaction (C) gives Hoffman product as the major product. The reason is the nature of the base. In option C , we can see that due to the bulky nature of t-butoxide it can abstract hydrogen from stearic free position only. Hence it disobeys satzeff rule.
Consider the following reaction:a)CH33CHOHCH3→ conc.H2SO4b)CH32CHCHBrCH3→ alc.KOHc) CH32CHCHBrCH3→ CH33O−K+d) Which of these reaction(s) will not produce Saytzeff product?