lf the ionisation energy of Na is 495.8 kJ mol-1, the electron affinity of Cl is 349.4 kJ mol-1 and lattice energy is 776 kJ mol-1, the true statement for the formation of ionic bondin NaCI is
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a
total energy released per mole of NaCl formed is 628.6 kJ
b
the ionic bond formed is unstable
c
the total energy absorbed per mole of NaCl formed is 1125.4 kJ
d
net energy released in this process is 629.6kJ
answer is D.
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Detailed Solution
Na(g)+495.8⟶Na+(g)+e− . . . (i) Cl(g)+e−⟶Cl−(g)+349.4 Na+(g)+Cl−(g)⟶NaCl(s)+776 kJ mol−1Total energy released per mole of NaCl formed = 776 + 349.4 = 1125.4 kJTotal energy absorbed in step (i) = 495.8 kJNet energy released = 629.6 kJThus, a stable ionic bond is formed between NaCl.