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Q.

The pressure at which equilibrium constant in term of pressure is found to be equal to that in terms of mole fraction for the equilibrium, PCl5(g)⇌PCl3(g)+Cl2(g) is :

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answer is 1.

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Detailed Solution

KP=Kx(P)Δng∴KP=Kx(P) Thus, Kp=Kx, when P=1 atm

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The pressure at which equilibrium constant in term of pressure is found to be equal to that in terms of mole fraction for the equilibrium, PCl5(g)⇌PCl3(g)+Cl2(g) is :