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Pure gas –A was taken in a closed container at an initial pressure of 5atm the pressure in the container changed due to the reactionsAg⇌Bg+2CgCg⇌Bg+DgIf the total pressure due to the mixture of gases A, B,C and D was found to be 10atm at equilibrium in which pressure due to C was 3 atm then kp for the first equilibrium is

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answer is 9.

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Detailed Solution

A5−x⇌Bx+y+2C2x−yC2x−y⇌By+x+DyPA+PB+PC+PD=5−x+x+y+2x−y+y=2x+y+5=10⇒2x+y=5−−−1PC=2x−y=3 . . . .2From 1 and 2 , x = 2 ⇒y=1PA=5−2=3PB=3 PC =3Kp=32×33=9

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