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Chemical Equilibrium

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By Expert Faculty of Sri Chaitanya
Question

Pure gas –A was taken in a closed container at an initial pressure of 5atm the pressure in the container changed due to the reactions

AgBg+2Cg

CgBg+Dg

If the total pressure due to the mixture of gases A, B,C and D was found to be 10atm at equilibrium in which pressure due to C was 3 atm then kp for the first equilibrium is

Moderate
Solution

A5xBx+y+2C2xy

C2xyBy+x+Dy

PA+PB+PC+PD=5x+x+y+2xy+y=2x+y+5=10

2x+y=51

PC=2xy=3 . . . .2

From 1 and 2   ,  x = 2 

y=1

PA=52=3

PB=3      PC=3

Kp=32×33=9


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