For the reaction 2H(g)⟶H2(g), the sign of ΔH and ΔSrespectively are
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a
+,-
b
+, +
c
-,+
d
-,-
answer is D.
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Detailed Solution
ΔH=−ve(H−H bond formed )ΔS=−veΔng=−12H→H2 the entropy of products is less than the reactants .so the ∆S=-ve from Gibbs equation ∆G=∆H-T.∆S ∆G=∆H+T.∆S(∆S=-ve)for spontaneous reaction ∆G=-veso the above reaction ∆H is -ve