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Q.

For the reaction 2H(g)⟶H2(g), the sign of ΔH and ΔSrespectively are

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a

+,-

b

+, +

c

-,+

d

-,-

answer is D.

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Detailed Solution

ΔH=−ve(H−H bond formed )ΔS=−veΔng=−12H→H2  the entropy of products is less than the reactants .so the ∆S=-ve from Gibbs equation ∆G=∆H-T.∆S ∆G=∆H+T.∆S(∆S=-ve)for spontaneous reaction  ∆G=-veso the above reaction ∆H is -ve
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