Statement 1: The borax Na2B4O5 OH4. 8H2O is a useful as primary standard for titrating against acids.Statement 2: Aqueous solution of borax contains equal amounts of weak acid and its salt.
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a
Both statements 1 and 2 are correct
b
Statement 1 is correct and statement 2 is incorrect
c
Statement 1 is incorrect and statement 2 is correct
d
Both statements 1 and 2 are incorrect
answer is A.
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Detailed Solution
Na2B4O5 OH4. 8H2O + 2HCl → 2NaCl + 4H3BO3 + 5H2OIndicator methyl orange pH range 3.1−4.4In water, borax gives both BOH3 and BOH4− and only the BOH4− reacts with HIReason : B4O5OH42− + 5H2O ⇌ 3BOH3weak acid + 2 BOH4-its saltthus acts as a buffer.