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Q.

Statement I: Hydrogen reacts faster with halogens than deuterium.Statement II : The activation energy of hydrogen is less than that of deuterium.

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a

Statement I and Statement II are true.

b

Statement I is true and  statement II is false.

c

Statement I is false and Statement II is true.

d

Statement I and Statement II are false.

answer is A.

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Detailed Solution

Reactivity of X2 with H2& D2H2+X2→2HX ;r1 D2+X2→2DX;r2rate :  r1>r2              Ea:(Ea)1 < (Ea)2  Ea: The minimum energy suplied to the reactants inorder to form the activated complex is called "Ea"In case of D2 reaction the D-D bond energy greater than that of H2 Bond dissociation energy, therefore in order to activate D2 require more energy.
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