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Which of the following complex ions is not diamagnetic ?

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By Expert Faculty of Sri Chaitanya
a
Ti(en)2NH324+
b
CrNH363+
c
ZnNH362+
d
ScH2O3NH333+

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detailed solution

Correct option is B

CrNH36+3CrZ=24 ......Ar4s13d5Cr+3  . ......  Ar3d3Irrespective of the field strength of ligands in octahedral Cr+3 complexes rearrangement does not occur.Hybridization is d2sp3.  μs=33+2  B.M.1  ......   Ti+4 .....Ar3.....  Zn+2.....Ar3d104.....  Sc+3....ArAll these species do not have unpaired electrons.


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