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Q.

Which of the following complex ions is not diamagnetic ?

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a

Ti(en)2NH324+

b

CrNH363+

c

ZnNH362+

d

ScH2O3NH333+

answer is B.

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Detailed Solution

CrNH36+3CrZ=24 ......Ar4s13d5Cr+3  . ......  Ar3d3Irrespective of the field strength of ligands in octahedral Cr+3 complexes rearrangement does not occur.Hybridization is d2sp3.  μs=33+2  B.M.1  ......   Ti+4 .....Ar3.....  Zn+2.....Ar3d104.....  Sc+3....ArAll these species do not have unpaired electrons.
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