First slide
Structural isomerism
Question

Which of the following pairs represents linkage isomers?

Easy
Solution

Linkage isomers are caused due to the presence of ambidentate ligands. PdPh32NCS2andPdPh32SCN2 are linkage isomers due to SCN, an ambidentate ligand. Thus, SCN can linked to Pd by both N as well as S through their lone pairs.

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