Questions
Which of the following pairs represents linkage isomers?
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a
CuNH34PtCl4 and PtNH34CuCl4
b
PdPh32NCS2 and PdPh32SCN2
c
CoNH35NO3SO4 and CoNH35SO4NO3
d
PtCl2NH34Br and PtBr2NH34Cl2
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Correct option is B
Linkage isomers are caused due to the presence of ambidentate ligands. PdPh32NCS2 and PdPh32SCN2 are linkage isomers due to SCN, an ambidentate ligand. Thus, SCN can linked to Pd by both N as well as S through their lone pairs.Similar Questions
The existence of two different coloured complexes with the composition of is due to
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