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Q.

Which one of the following is an inner orbital complex as well as diamagnetic in nature?

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a

CoNH363+

b

CrNH363+

c

NiNH362+

d

ZnNH362+

answer is A.

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Detailed Solution

In ZNNH362+, Zn exists as Zn2+ 30Zn:3d10,4s2Zn2+: 3d10 ; Thus, no unpaired electron but it is outer orbital complex.In [Co(NH3)6]3+, Co exists as Co3+27Co: 3d7, 4s2Co3+: 3d6; It is d2sp3 hybridized, inner orbital complex with 3 electron paired in 3d.
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Which one of the following is an inner orbital complex as well as diamagnetic in nature?