Balmer gives an equation for wavelength of visible radiation of H-spectrum as λ=kn2n2−4. The value of k in terms of Rydberg’s constant R is
R
4R
R/4
4/R
1λ = R Z21n12 − 1n22. For H−atom Z=1.
For visible radiation, n1=2
∴ 1λ = R 12 2 − 1n 2 ⇒ λ=4n2Rn2−4=k n2n2−4 ⇒ k=4R.