Consider a gas of triatomic molecules. The molecules are assumed to be triangular and made of massless rigid rods whose vertices are occupied by atoms. The internal energy of a mole of the gas at temperature T is :
Degrees of freedom for a non linear triatomic molecule = Three Translation + Three Rotation = 6
(or) f=3A-B=3(3)-3=6 A=no. of atoms and B= no of restrictions