An ideal monoatomic gas is confined in a horizontal cylinder by a spring loaded piston (as shown in the figure). Initially the gas is at temperature T1, pressure P1 and volume V1 and the spring is in its relaxed state. The gas is then heated very slowly to temperature T2, pressure P2 and volume V2. During this process the piston moves out by a distance x.Assume that pressure in the chamber containing spring remains the same throughout the motion of the piston. Ignoring the friction between the piston and the cylinder, the correct statement(s) is (are)
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a
If V2=2V1 and T2=3T1, then the energy stored in the spring is 14P1V1
b
If V2=2V1 and T2=3T1 , then the change in internal energy is 3P1V1
c
If V2=3V1 and T2=4T1 , then the work done by the gas is 73P1V1
d
If V2=3V1 and T2=4T1 , then the heat supplied to the gas is 176P1V1
answer is A.
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Detailed Solution
Ideal mono atomic gas γ=53Spring released state Fsp=0 Gas heated slowly (external agent)(Process is not adiabatic / isobaric/ isochoric). Initial conditions Final conditions P1 P2V1 V2T1 T2 (A) V2=2V1T2=3T1,P2=? From ideal gas equation P1V1P2V2=nRT1nRT2⇒P1P212=13⇒P2=3P12Equilibrium of pistonP2=P1+Pspring ⇒3P12=P1+kxA⇒P12=KxA∴ Sping energy: U=12Kxsp2=Kxsp22K⇒U=12P12xA(x)2=12P12(Ax)=14P1V2−V1⇒U=P1V14 Ans. A correct (B) If V2=2V1 and T2=3T1 Change in internal energy of gas ΔU=nCV(ΔT) [valid irrespective of the process ⇒ΔU=P1V1RT13R23T1−T1=3P1V1Ans. A Correct (C) If V2=3V1 and T2=4T1P=P1+kXAwork done by the gas is W=∫PdV=∫P1+kxAdV=∫P1dV+∫kxAAdx⇒W=P1V2−V1+kx22 Using ,P1V1P2V2=nRT1nRT2⇒P1P213=14⇒P2=43P1Using ,P=P1+kxA⇒43P1=P1+kxA⇒kx=P1A3 Also, V2=v1+Ax⇒3V1=V1+Ax⇒x=2V1AThus W=P1V2−V1+kx22=P13V1−V1+12×P1A3×2V1A=73P1V1Option C is correct Heat supplied =Q=W+ΔU⇒Q=73P1V1+32P2V2−P1V1⇒Q=73P1V1+3243P13V1−P1V1=416P1V1Option D is wrong