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Q.

If the intermolecular forces vanish away, the volume occupied by the molecules contained in 4.5 kg water at standard temperature and pressure will be given by

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a

5.6m3

b

4.5m3

c

11.2 L

d

11.2m3

answer is A.

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Detailed Solution

μ=Mass of waterMolecular wt. of water=4.5 kg18×10-3kg=250 T=273 K and P=105 N/m2 (STP) From PV = μRT, ⇒  V=μRTP=250×8.3×273105=5.66m3
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If the intermolecular forces vanish away, the volume occupied by the molecules contained in 4.5 kg water at standard temperature and pressure will be given by