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Q.

n mole of a perfect gas and undergoes a cyclic process ABCA (see figure) consisting of the following processes.A→B : Isothermal expansion at temperature T so that the volume is doubled from V1  to V2=2V1  and pressure changes from P1  to P2.B→C: Isobaric compression at pressure P2 to initial volume  V1C→A: Isochoric change leading to change of pressure from P2  to P1.   Total work done in the complete cycle ABCA is :

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a

nRTln2+12

b

0

c

nRTln2

d

nRTln2−12

answer is D.

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Detailed Solution

At point A and B temperature is same.T1=T2⇒P1V1nR=P2V2nR ⇒P2=P12Work done in isothermal process, WAB=nRTlnVfVi ⇒WAB=P1 V1 ln2V1V1⇒WAB=P1V1ln2Work done in isobaric process,WBC=P2V1-V2⇒WBC=P2V1-2V1⇒WBC=P12-V1⇒WBC=−P1V12Work done in isochoric process, WCA=0Hence, Net work done, WABCA=P1V1ℓn2−P1V12As per ideal gas equation, P1V1=nRT⇒WABCA=nRTln2-12
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